• Common types, synthetic methods and crosslinking methods of acrylic resins
    Common types, synthetic methods and crosslinking methods of acrylic resins

    2023-03-02

    Acrylic resin is made of acrylic ester and methacrylate and other alene monomers copolymerization resin, through the selection of different resin structure, different formula, production process and solvent composition, can be synthesized different types, different performance and different application of acrylic resin, Acrylic resin can be divided into thermoplastic acrylic resin and thermosetting acrylic resin according to the difference of structure and film forming mechanism. The main absorption peak of acrylic resin synthesized by copolymerization of acrylic ester and methacrylate monomer is outside the range of solar spectrum, so the acrylic resin paint has excellent light resistance and outdoor aging performance. Thermoplastic acrylic resin in the film forming process does not occur further crosslinking, so its relative molecular weight is larger, has good light and color preservation, water and chemical resistance, fast drying, convenient construction, easy construction recoating and rework, aluminum powder preparation of aluminum powder whiteness, good positioning. Thermoplastic acrylic resin is widely used in automobile, electrical appliance, machinery, construction and other fields. Thermosetting acrylic resin refers to a certain functional group in the structure, in the paint through and added amino resin, epoxy resin, polyurethane and other functional groups reaction to form a network structure, thermosetting resin is generally relatively low molecular weight. Thermosetting acrylic coatings have excellent fullness, gloss, hardness, solvent resistance, weather resistance, no color change in high temperature baking, no yellowing. The most important application is to make amino acrylic paint with amino resin, which is widely used in cars, motorcycles, bicycles, coil steel and other products. According to the mode of production, it can be divided into: 1.Emulsion polymerization is through monomer, initiator and its reaction solvent reaction polymerization, the general resin for solid content of 50% resin solution! Is containing about 50% of the solvent resin, the general reaction with the solution of benzene (toluene or xylene), esters (ethyl acetate, butyl acetate), is generally single or mixed! Solid emulsion type acrylic resin has solvent immutability! Generally due to the choice of solvents and the product performance is not the same! Generally have a certain color number! The glass transition temperature is low, because the reaction is usually done with no methyl acrylate! Solid this type of resin can have a higher solid content, up to 80%! Can do high solid paint, production is simple! But because of solvent immutability, transportation is not convenient! 2, suspension polymerization is a more complex production process, is generally used as a method for the production of solid resin! Solid acrylic resin, which is generally used with methyl acrylate down reaction polymerization! Acrylates without methyl are generally with a certain...

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  • Water-based acrylic emulsion production process
    Water-based acrylic emulsion production process

    2023-02-23

    Preparation method of waterborne acrylic emulsion 1.The preparation of water-based acrylic emulsion: the raw materials including acrylic hard monomer, acrylic soft monomer and acrylic functional monomer all acrylic monomer, emulsifier, water added to the pre-emulsifying kettle, emulsifying 30 ~ 40min.A non-stratified emulsion is obtained. Then the remaining water, remaining emulsifier and buffer are added into the polymerization reactor, and the temperature is raised to 78 ~ 80℃. The emulsion is put in, and the initiator is added for 20 ~ 30min. The remaining emulsion and remaining initiator are added, and the droplets are finished in 3 ~ 4h. Then the polymerization reactor was heated to 85 ~ 90℃ to hold heat for 1 ~ 2 hours, and the temperature was lowered to 45 ~ 50℃. pH regulator was added to adjust the PH value of the reaction system to between 6 ~ 7. That is to prepare water-based acrylic emulsion. 2.Common equipment required for the preparation of water-based acrylic emulsion preemulsification kettle → drip adding kettle → reaction kettle → vertical condenser → filter → stirring kettle → filling machine → need a vacuum system, nitrogen system, water cooling system, pure water equipment Water-based acrylic emulsion features 1.Water-based acrylic emulsion is commonly used in thermosetting resin, the amount of thermosetting resin is relatively large, and widely used. Water-based acrylic emulsion also has many modifiers, accelerators, additives, etc., can be composed of a variety of combinations, so as to obtain different properties of epoxy curing system, to meet the requirements of various properties and processes 2.The stability of water-based acrylic emulsion is affected by temperature. The stability of emulsion is better at low temperature. 3.Water-based acrylic emulsion in the polymerization process to water as a solvent, to avoid the use of expensive organic solvents and recovery solvent trouble, but also reduce the risk of fire and pollution. It is cheap, pollution-free, safe and convenient, energy saving and other advantages make emulsion polymerization more and more widely used.

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  • Introduction of six features of water-based acrylic emulsion
    Introduction of six features of water-based acrylic emulsion

    2023-02-20

    Together to understand the characteristics of water-based acrylic emulsion! 1.Excellent adhesion The polymer structure of water-based acrylic emulsion contributes to the flow and wettability of molecular chains on the substrate surface, making the coating and substrate molecules in close contact, to achieve high adhesion 2.High load-bearing capacity of the makeup filler can significantly reduce the cost Waterborne acrylic emulsion has excellent fillability, the total solid content of the coating formula can reach 60%. Among them, the ratio of resin to filler can reach 1:2, which significantly reduces the formulation and use cost of waterborne wood lacquer. 3.Zero VOC safety and environmental protection Water-based acrylic emulsion itself does not contain VOC, and can be formed at room temperature without film forming agent. Paints formulated in this way can have zero VOC content. 4.Excellent water resistance Aqueous acrylic emulsion does not contain ordinary acrylic emulsion used surfactants, and has a special design of hydrophobic groups. Therefore, water-based acrylic emulsion has excellent moisture resistance, which can prevent the penetration of water molecules to the substrate after the film is dried, so as to achieve the effect of waterproof and moisture-proof. 5.Excellent weather resistance The molecular structure of water-based acrylic emulsion adopts UV-stabilized monomer structure, and the emulsion is specially designed, which can make TIO2 fully evenly dispersed in the emulsion, reduce the influence of UV on the emulsion, and effectively protect the substrate. 6.Excellent pigment dispersion Water-based acrylic emulsion and a variety of water-based color paste compatibility is good, so that the function of fillers and pigments get the maximum play, paint color bright. Water-based acrylic emulsion and a variety of water-based color paste compatibility is good, so that the function of fillers and pigments get the maximum play, paint color bright.

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  • Precautions and reason analysis of water-based film coating process
    Precautions and reason analysis of water-based film coating process

    2023-02-16

    Water-based coating is an effective means to process the surface of printed matter, to improve the gloss and strength of the surface of printed matter, enhance the aesthetic effect, temperature resistance, water resistance, wear resistance, improve the grade of printed matter and commodity value. Therefore, to measure the quality of the coating, it is also necessary to examine the brightness, strength, adhesion and other aspects of the coating. Water-based coating is an effective means to process figures on the surface of printed matter, to improve the gloss and strength of printed matter surface, enhance the aesthetic effect, temperature resistance, water resistance, wear resistance, improve the grade of printed matter and commodity value, so to measure the quality of the film Fuji Star, also need to examine the brightness, strength, adhesion and other aspects of the film. The development of water-based laminating machine makes the water-based laminating process widely promoted and applied. Water-based wet laminating is favored by the majority of customers for its high strength, high grade, easy recovery, no pollution and other characteristics of laminating printed matter. Water-based film coating process has just been promoted, because customers do not know much about this process, more concerns about film, afraid of problems, in view of this, had done a lot of tests for customers in advance, such as:  in order to test the combined printing of water-coated printed matter with temperature resistance, humidity resistance and oil resistance, has done the relevant film coating test in the early use of the machine, whether temperature resistance, humidity resistance and oil resistance, can meet the requirements of the film coating products. Laminating process is more complex, in normal production still need to pay attention to the following problems:Powder printing Print product dusting Because water-based glue can dissolve powder on the surface of printed matter, so when the coated product snowflake point when the post-press process, it will feel incomprehensible, in fact, the reason is very simple, water-based glue itself is also limited by solubility, if the printing powder is too large, the excess part can not be completely dissolved by glue plate making, there will be a large area of snow. There are three ways to deal with this situation: 1. Coordinate the upper and lower processes to minimize the amount of powder spraying during printing 2. The amount of glue water should be increased appropriately to increase the ability of the glue to dissolve the powder; Digital printing post-press processing 3. Clean the surface of the printed matter with suspended powder spraying before coating Clean Due to the water-based coating adhesive drying quickly, if static no flow, will dry into rubber equipment maintenance and maintenance, into a solid block. If attached to the rubber roll or pressure roll, it will cause local glue is too small, or pre...

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